{"id":15672,"date":"2023-09-14T07:26:26","date_gmt":"2023-09-14T07:26:26","guid":{"rendered":"http:\/\/quartz-grinding.com\/?p=15672"},"modified":"2023-09-14T07:26:29","modified_gmt":"2023-09-14T07:26:29","slug":"what-are-the-effects-of-different-impurity-elements-on-the-quality-of-high-purity-quartz-products","status":"publish","type":"post","link":"https:\/\/www.quartz-grinding.com\/es\/what-are-the-effects-of-different-impurity-elements-on-the-quality-of-high-purity-quartz-products\/","title":{"rendered":"\u00bfCu\u00e1les son los efectos de los diferentes elementos impuros sobre la calidad de los productos de cuarzo de alta pureza?"},"content":{"rendered":"

Los elementos impuros tienen un impacto significativo en la calidad de los productos de cuarzo de alta pureza, y el contenido de metales alcalinos, metales de transici\u00f3n, elementos Al y B es un indicador clave de las materias primas de cuarzo de alta pureza. Los requisitos para el contenido de impurezas var\u00edan seg\u00fan el prop\u00f3sito del vidrio de cuarzo preparado, pero la tendencia general es que cuanto m\u00e1s bajo, mejor.<\/p>\n\n\n\n

\"\"<\/a><\/figure>\n\n\n\n

Elemento de metal alcalino<\/h2>\n\n\n\n

Los elementos de metales alcalinos en la arena de cuarzo incluyen principalmente elementos de litio (Li), sodio (Na) y potasio (K). Estos elementos se difunden f\u00e1cilmente y son qu\u00edmicamente activos en el cuarzo, lo que los hace relativamente f\u00e1ciles de eliminar. Sin embargo, suponen un gran da\u00f1o. A altas temperaturas, estos elementos act\u00faan como fundentes, provocando malos fen\u00f3menos como la p\u00e9rdida de transparencia y la deformaci\u00f3n a alta temperatura en el vidrio a alta temperatura. Catalizan la cristalizaci\u00f3n, afectan la estabilidad t\u00e9rmica de los productos de cuarzo y tambi\u00e9n afectan las propiedades \u00f3pticas y t\u00e9rmicas del vidrio de cuarzo, reduciendo la vida \u00fatil de los semiconductores. El coeficiente diel\u00e9ctrico y la p\u00e9rdida diel\u00e9ctrica del vidrio de cuarzo aumentar\u00e1n, mientras que la velocidad de propagaci\u00f3n y la resistencia mec\u00e1nica de La luz en los productos de cuarzo disminuir\u00e1.<\/p>\n\n\n\n

Reducir el contenido de elementos de metales alcalinos es beneficioso para mejorar el punto de reblandecimiento de los crisoles de cuarzo de alta pureza, mejorar su resistencia a la deformaci\u00f3n y mejorar el rendimiento de los monocristales. La arena est\u00e1ndar de IOTA requiere un total de 2,4 elementos de metales alcalinos \u00d7 10-6, el cuarzo de alta pureza total requerido para crisoles semiconductores utilizados para tubos de proceso, procesamiento de obleas de silicio, bloques de cuarzo y extracci\u00f3n de silicio monocristalino es 1,4 \u00d7 10-6, CZ Los crisoles requieren un total de 0,5 \u00d7 10-6, y el total requerido para la arena de cuarzo de pureza ultra alta utilizada para obleas de silicio de 12 pulgadas o m\u00e1s es 0,08 \u00d7 10-6.<\/p>\n\n\n\n

Elementos de metales de transici\u00f3n<\/h2>\n\n\n\n

Los elementos de metales de transici\u00f3n dopados con arena de cuarzo incluyen principalmente hierro (Fe), zinc (Zn), cobre (Cu), cromo (Cr), manganeso (Mn), n\u00edquel (Ni) y otros elementos. Estos elementos tienen un impacto significativo en los productos de cuarzo y los oligoelementos pueden disolverse en el silicio fundido para evitar la conductividad, lo que perjudica la previsibilidad y confiabilidad del instrumento. El impacto objetivo sobre los productos de cuarzo es producir manchas de color o causar decoloraci\u00f3n a alta temperatura, reduciendo la transmitancia de la luz.<\/p>\n\n\n\n

En aplicaciones de fibra \u00f3ptica, puede causar microdesigualdades, aumentar la p\u00e9rdida de fibra e incluso provocar distorsi\u00f3n de la se\u00f1al. Sin embargo, en aplicaciones de semiconductores, el peque\u00f1o contenido de elementos de metales de transici\u00f3n en el producto puede promover el crecimiento de cristales.<\/p>\n\n\n\n

Elemento de aluminio de boro<\/h2>\n\n\n\n

El contenido del elemento boro (B) en la arena de cuarzo est\u00e1 directamente relacionado con la geolog\u00eda del mineral de cuarzo. Los iones B pueden entrar en la estructura de las mol\u00e9culas de silicato y generar fuertes enlaces qu\u00edmicos, y no s\u00f3lo en minerales que contienen boro. Una cantidad excesiva de elemento B tiene un impacto fatal en la extracci\u00f3n del silicio monocristalino, y un elemento B de 1\u00d710-6 puede reducir significativamente la resistencia del silicio monocristalino. Los crisoles de cuarzo de alta pureza requieren altos requisitos de B, con un contenido de elementos inferior a 0,04 \u00d7 10-6.<\/p>\n\n\n\n

El elemento aluminio (Al) existe principalmente en minerales impuros como feldespato, arcilla y mica en arena de cuarzo. Es el elemento impureza m\u00e1s abundante en la arena de cuarzo, y el Al puede ingresar a la estructura tetra\u00e9drica de Si-O para reemplazar al silicio, formando una estructura de Al-O. Despu\u00e9s de que Al3+ reemplaza al Si4+, se seleccionan elementos de metales alcalinos o incluso elementos de metales de transici\u00f3n para compensar la carga y equilibrar la carga. El Al que ingresa al esqueleto de Si-O no se eliminar\u00e1 f\u00e1cilmente. El Al tiene poco efecto sobre los semiconductores, pero tiene un impacto significativo sobre el vidrio de cuarzo utilizado para fuentes de luz el\u00e9ctrica. Debido a que la IA puede colorear productos de cuarzo bajo ciertas condiciones, afecta la transmitancia espectral y, por lo tanto, afecta la eficiencia de la luz. La arena est\u00e1ndar de IOTA requiere un contenido de elementos Al (12-18) \u00d7 10-6.<\/p>\n\n\n\n

Elementos no met\u00e1licos<\/h2>\n\n\n\n

Los elementos no met\u00e1licos de la arena de cuarzo est\u00e1n compuestos principalmente de ox\u00edgeno (O), hidr\u00f3geno (H), nitr\u00f3geno (N) y otros elementos. La principal masa de ox\u00edgeno es el SiO2, mientras que otros existen en forma de H2O, N2 y O2. La fractura de los enlaces Si-O en SiO2 dar\u00e1 como resultado defectos que se combinan con OH o H para formar grupos SiH o SiOH. Los grupos hidroxilo son tanto defectos de impurezas como defectos estructurales de la red.<\/p>\n\n\n\n

Los grupos hidroxilo tienen un impacto significativo en las propiedades del cuarzo y del vidrio de cuarzo. En primer lugar, la presencia de grupos hidroxilo reduce la estabilidad qu\u00edmica del cuarzo. En segundo lugar, los grupos hidroxilo aumentan la porosidad de la estructura del cuarzo, reducen la densidad, disminuyen la fuerza de uni\u00f3n y reducen la velocidad de propagaci\u00f3n del sonido en el vidrio de cuarzo. Los grupos hidroxilo tambi\u00e9n pueden reducir la viscosidad del cuarzo, y la presencia de grupos hidroxilo a bajas temperaturas puede provocar una disminuci\u00f3n m\u00e1s significativa de la viscosidad. Adem\u00e1s, los grupos hidroxilo tambi\u00e9n afectan la pureza de los productos electr\u00f3nicos, reducen la temperatura de ablandamiento del cuarzo, promueven la precipitaci\u00f3n de cristales, reducen el \u00edndice de refracci\u00f3n del cuarzo y afectan la uniformidad \u00f3ptica del vidrio de cuarzo.<\/p>","protected":false},"excerpt":{"rendered":"

Los elementos impuros tienen un impacto significativo en la calidad de los productos de cuarzo de alta pureza, y el contenido de metales alcalinos, metales de transici\u00f3n, elementos Al y B es un indicador clave de [\u2026]<\/p>","protected":false},"author":1,"featured_media":15674,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"default","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","ast-disable-related-posts":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center 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