{"id":15672,"date":"2023-09-14T07:26:26","date_gmt":"2023-09-14T07:26:26","guid":{"rendered":"http:\/\/quartz-grinding.com\/?p=15672"},"modified":"2023-09-14T07:26:29","modified_gmt":"2023-09-14T07:26:29","slug":"what-are-the-effects-of-different-impurity-elements-on-the-quality-of-high-purity-quartz-products","status":"publish","type":"post","link":"https:\/\/www.quartz-grinding.com\/nl\/what-are-the-effects-of-different-impurity-elements-on-the-quality-of-high-purity-quartz-products\/","title":{"rendered":"Wat zijn de effecten van verschillende onzuiverheidselementen op de kwaliteit van hoogzuivere kwartsproducten?"},"content":{"rendered":"

Onzuiverheidselementen hebben een aanzienlijke invloed op de kwaliteit van hoogzuivere kwartsproducten, en het gehalte aan alkalimetalen, overgangsmetalen, Al- en B-elementen is een sleutelindicator voor hoogzuivere kwartsgrondstoffen. De vereisten voor het gehalte aan onzuiverheidselementen vari\u00ebren afhankelijk van het doel van het geprepareerde kwartsglas, maar de algemene trend is dat hoe lager hoe beter.<\/p>\n\n\n\n

\"\"<\/a><\/figure>\n\n\n\n

Alkalimetaalelement<\/h2>\n\n\n\n

De alkalimetaalelementen in kwartszand omvatten voornamelijk lithium (Li), natrium (Na) en kalium (K) elementen. Deze elementen zijn gemakkelijk verspreid en chemisch actief in kwarts, waardoor ze relatief eenvoudig te verwijderen zijn. Ze richten echter grote schade aan. Bij hoge temperaturen werken deze elementen als fluxen, waardoor slechte verschijnselen ontstaan zoals verlies aan transparantie en vervorming bij hoge temperaturen in glas met hoge temperaturen. Ze katalyseren de kristallisatie, be\u00efnvloeden de thermische stabiliteit van kwartsproducten en be\u00efnvloeden ook de optische en thermische eigenschappen van kwartsglas, waardoor de levensduur van halfgeleiders wordt verkort. De di\u00eblektrische co\u00ebffici\u00ebnt en het di\u00eblektrisch verlies van kwartsglas zullen toenemen, terwijl de voortplantingssnelheid en mechanische sterkte van kwartsglas zullen toenemen. licht in kwartsproducten zal afnemen.<\/p>\n\n\n\n

Het verminderen van het gehalte aan alkalimetaalelementen is gunstig voor het verbeteren van het verwekingspunt van kwartskroezen met een hoge zuiverheid, het verbeteren van hun vervormingsweerstand en het verbeteren van de opbrengst aan enkele kristallen. IOTA-standaardzand vereist in totaal 2,4 alkalimetaalelementen \u00d7 10-6, het totaal vereiste zeer zuivere kwarts voor halfgeleiderkroezen die worden gebruikt voor procesbuizen, verwerking van siliciumwafels, kwartsblokken en monokristallijne siliciumextractie is 1,4 \u00d7 10-6, CZ smeltkroezen hebben in totaal 0,5 x 10-6 nodig, en het totaal dat nodig is voor kwartszand met ultrahoge zuiverheid dat wordt gebruikt voor siliciumwafels van 12 inch of groter is 0,08 x 10-6.<\/p>\n\n\n\n

Overgangsmetalen elementen<\/h2>\n\n\n\n

De overgangsmetaalelementen die in kwartszand zijn gedoteerd, omvatten voornamelijk ijzer (Fe), zink (Zn), koper (Cu), chroom (Cr), mangaan (Mn), nikkel (Ni) en andere elementen. Deze elementen hebben een aanzienlijke impact op kwartsproducten en sporenelementen kunnen oplossen in siliciumsmelt om geleiding te voorkomen, wat de voorspelbaarheid en betrouwbaarheid van het instrument schaadt. De objectieve impact op kwartsproducten is het produceren van kleurvlekken of het veroorzaken van verkleuring bij hoge temperaturen, waardoor de lichttransmissie wordt verminderd.<\/p>\n\n\n\n

Bij glasvezeltoepassingen kan dit micro-oneffenheden veroorzaken, het vezelverlies vergroten en zelfs tot signaalvervorming leiden. Bij halfgeleidertoepassingen kan het kleine gehalte aan overgangsmetaalelementen in het product echter de kristalgroei bevorderen.<\/p>\n\n\n\n

Borium aluminium element<\/h2>\n\n\n\n

Het gehalte aan boorelement (B) in kwartszand houdt rechtstreeks verband met de geologie van kwartserts. B-ionen kunnen het raamwerk van silicaatmoleculen binnendringen en sterke chemische bindingen genereren, in plaats van alleen in boorhoudende mineralen. De overmatige hoeveelheid B-element heeft een fatale invloed op het trekken van monokristallijn silicium, en een 1\u00d710-6 B-element kan de weerstand van monokristallijn silicium aanzienlijk verminderen. Hoogzuivere kwartskroezen stellen hoge eisen aan B, met een elementgehalte van minder dan 0,04 \u00d7 10-6.<\/p>\n\n\n\n

Aluminiumelement (Al) komt voornamelijk voor in onzuivere mineralen zoals veldspaat, klei en mica in kwartszand. Het is het meest voorkomende onzuiverheidselement in kwartszand, en Al kan het Si-O-tetra\u00ebdrische raamwerk binnendringen om silicium te vervangen en een Al-O-structuur te vormen. Nadat Al3+ Si4+ heeft vervangen, worden alkalimetaalelementen of zelfs overgangsmetaalelementen geselecteerd om de lading te compenseren en de lading in evenwicht te brengen. Het Al dat het Si-O-skelet binnendringt, zal niet gemakkelijk worden verwijderd. Al heeft weinig effect op halfgeleiders, maar heeft een aanzienlijke impact op kwartsglas dat wordt gebruikt voor elektrische lichtbronnen. Omdat AI onder bepaalde omstandigheden kwartsproducten kan kleuren, heeft dit invloed op de spectrale transmissie en daarmee op de lichteffici\u00ebntie. IOTA-standaardzand vereist een Al-elementgehalte (12-18) \u00d7 10-6.<\/p>\n\n\n\n

Niet-metalen elementen<\/h2>\n\n\n\n

De niet-metalen elementen in kwartszand bestaan voornamelijk uit zuurstof (O), waterstof (H), stikstof (N) en andere elementen. De belangrijkste hoeveelheid zuurstof is SiO2, terwijl andere bestaan in de vorm van H2O, N2 en O2. Het breken van Si-O-bindingen in SiO2 zal resulteren in defecten die samen met OH of H SiH- of SiOH-groepen vormen. Hydroxylgroepen zijn zowel onzuiverheidsdefecten als structurele netwerkdefecten.<\/p>\n\n\n\n

Hydroxylgroepen hebben een aanzienlijke invloed op de eigenschappen van kwarts en kwartsglas. Ten eerste vermindert de aanwezigheid van hydroxylgroepen de chemische stabiliteit van kwarts. Ten tweede verhogen hydroxylgroepen de porositeit van de kwartsstructuur, verminderen de dichtheid, verminderen de bindingskracht en verminderen de voortplantingssnelheid van geluid in kwartsglas. Hydroxylgroepen kunnen ook de viscositeit van kwarts verlagen, en de aanwezigheid van hydroxylgroepen bij lage temperaturen kan een significantere afname van de viscositeit veroorzaken. Bovendien be\u00efnvloeden hydroxylgroepen ook de zuiverheid van elektronische producten, verlagen ze de verwekingstemperatuur van kwarts, bevorderen ze kristalprecipitatie, verminderen ze de brekingsindex van kwarts en be\u00efnvloeden ze de optische uniformiteit van kwartsglas.<\/p>","protected":false},"excerpt":{"rendered":"

Onzuiverheidselementen hebben een aanzienlijke invloed op de kwaliteit van hoogzuivere kwartsproducten, en het gehalte aan alkalimetalen, overgangsmetalen, Al- en B-elementen is een belangrijke indicator van [\u2026]<\/p>","protected":false},"author":1,"featured_media":15674,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"default","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","ast-disable-related-posts":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center 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