{"id":15836,"date":"2024-10-16T01:53:32","date_gmt":"2024-10-16T01:53:32","guid":{"rendered":"http:\/\/quartz-grinding.com\/?p=15836"},"modified":"2024-10-18T05:03:56","modified_gmt":"2024-10-18T05:03:56","slug":"silicon-after-grinding-by-mill-can-be-used-in-negative-electrode","status":"publish","type":"post","link":"https:\/\/www.quartz-grinding.com\/nl\/silicon-after-grinding-by-mill-can-be-used-in-negative-electrode\/","title":{"rendered":"Silicium verwerkt via maalmolen kan worden gebruikt in negatieve elektrode"},"content":{"rendered":"

Met de snelle ontwikkeling van de batterijtechnologie, silicium<\/a> wordt geleidelijk een potentieel negatief elektrodemateriaal. Al in de jaren 70 ontdekten mensen de elektrochemische reactie tussen lithium (Li)<\/a> en elementair silicium (Si). Door verwerking in een maalmolen, bijvoorbeeld een kogelmolen, kan silicium goed worden gebruikt in de negatieve elektroden van batterijen. <\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

Het reactiepotentieel van lithium-siliciumlegering (LixSi, 0 < x \u2264 4,4) neemt af met de toename van de lithi\u00ebringsgraad. Vanwege zijn uitstekende eigenschappen heeft silicium veel aandacht getrokken van de academische wereld en de industrie als de volgende generatie negatieve elektrodematerialen. We kunnen echter niet rechtstreeks zuiver silicium of silicium met een hoog gehalte gebruiken als negatieve elektrode van de batterij. Waarom? Laten we het hieronder analyseren:<\/p>\n\n\n\n

Redenen waarom zuiver silicium of silicium met een hoge zuiverheidsgraad niet als negatieve elektrode kan worden gebruikt<\/strong><\/h2>\n\n\n\n

 1. Het probleem van volume-expansie<\/strong><\/h3>\n\n\n\n

Het volume van silicium verandert met meer dan 280% wanneer het volledig gelithieerd is. Het lithium-invoegproces is als het blazen van lucht in een leeggelopen ballon<\/a>. Naarmate het gasgehalte toeneemt, blijft de ballon uitzetten. Terwijl het proces van het verwijderen van lithiumionen lijkt op het leeglopen van een ballon, en het volume terugkeert naar zijn oorspronkelijke grootte.<\/p>\n\n\n\n

Echter, als vast deeltje heeft silicium geen goede elastische vervorming zoals een ballon. Siliciumdeeltjes, met continue uitzetting en krimp, veroorzaken zeer waarschijnlijk ernstige scheuren en verpulvering van het anodemateriaal en de elektrodelaag. In deze situatie zal een nieuwe interface tussen het anodemateriaal en de elektrolyt worden gevormd, en dit zal resulteren in een negatieve impact op het elektrolytverbruik en de SEI-dikte.<\/p>\n\n\n\n

2.Het probleem van elektrische geleidbaarheid <\/strong><\/h3>\n\n\n\n

De elektronische geleidbaarheid van silicium met een hoge zuiverheid (< 10-5<\/sup> S\/cm) en de diffusiesnelheid van lithiumionen in silicium (10\u221214<\/sup>\u201410\u221213<\/sup> cm2<\/sup>\/s) zijn veel lager dan die van grafiet. De elektronische geleidbaarheid zou de transmissie van elektronen in anodemateriaal be\u00efnvloeden, dus een goed geleidend netwerk is van het grootste belang. Bovendien zou de ionische geleidbaarheid het proces van inbedden en extraheren van lithiumionen be\u00efnvloeden en de transmissieafstand verkorten.<\/p>\n\n\n\n

Dus, hoe lossen we dit probleem op? Het antwoord is om silicium en grafiet te combineren. <\/strong><\/h2>\n\n\n\n

Het toevoegen van grafiet aan siliciummateriaal kan de volumeverandering van de integrale composietelektrode bufferen. Onder de conditie van een laag siliciumgehalte (ongeveer 20%) worden de belangrijkste reactieplaatsen voor de vorming van de vaste elektrolytinterface (SEI) geleverd door grafietdeeltjes. Het toevoegen van grafiet aan silicium kan de diffusiviteit van de elektrode verbeteren en de verwerkbaarheid bij de productie van de elektrode verbeteren, waardoor een hogere energiedichtheid zou worden verkregen.<\/p>\n\n\n\n

Toepassingsperspectief van silicium verwerkt door maalmolen in negatieve elektrode van batterij<\/strong><\/h2>\n\n\n\n

Vanwege de hoge theoretische specifieke capaciteit en energiedichtheid kan silicium de prestaties van de batterij aanzienlijk verbeteren. Op silicium gebaseerde negatieve elektrodematerialen, zoals koolstofgecoat siliciumoxide, nanosiliciumkoolstof, siliciumnanodraad en amorfe siliciumlegering, hebben nu een brede toepassing in de velden van krachtbatterijen, energieopslagbatterijen en consumentenbatterijen. In de toekomst zal op silicium gebaseerd negatief elektrodemateriaal de focus van de batterij-industrie worden en grootschalige commerci\u00eble toepassing bereiken.<\/p>\n\n\n\n

Silicium dat in negatieve elektrodematerialen van batterijen wordt gebruikt, is voornamelijk in nanovorm. We kunnen nanosiliciumpoeder verkrijgen door middel van een maalmolen, bijvoorbeeld: kogel molen<\/strong>.<\/a> Tegelijkertijd is om de elektrochemische prestaties van silicium negatief elektrodemateriaal te verbeteren, modificatie van silicium noodzakelijk. Als een professionele fabrikant van poederapparatuur, Qingdao Epic Powder Machinery Co., Ltd<\/em><\/strong><\/em><\/strong>.<\/a> kan produceren kogelmolen en oppervlaktecoating modificatiesysteem<\/strong> voor siliciumverwerking. Als u gerelateerde behoeften en vragen hebt, neem dan contact op Qingdao-epos<\/a><\/strong>.<\/p>\n\n\n\n

Hieronder vindt u foto's ter referentie.<\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n
\"\"<\/figure>","protected":false},"excerpt":{"rendered":"

Met de snelle ontwikkeling van batterijtechnologie wordt silicium geleidelijk een potentieel negatief elektrodemateriaal. Al in de jaren 70 ontdekten mensen de elektrochemische reactie tussen lithium (Li) en elementair silicium [\u2026]<\/p>","protected":false},"author":1,"featured_media":15865,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"default","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","ast-disable-related-posts":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"set","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center 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