{"id":15672,"date":"2023-09-14T07:26:26","date_gmt":"2023-09-14T07:26:26","guid":{"rendered":"http:\/\/quartz-grinding.com\/?p=15672"},"modified":"2023-09-14T07:26:29","modified_gmt":"2023-09-14T07:26:29","slug":"what-are-the-effects-of-different-impurity-elements-on-the-quality-of-high-purity-quartz-products","status":"publish","type":"post","link":"https:\/\/www.quartz-grinding.com\/pt\/what-are-the-effects-of-different-impurity-elements-on-the-quality-of-high-purity-quartz-products\/","title":{"rendered":"Quais s\u00e3o os efeitos dos diferentes elementos de impureza na qualidade dos produtos de quartzo de alta pureza?"},"content":{"rendered":"

Os elementos de impureza t\u00eam um impacto significativo na qualidade dos produtos de quartzo de alta pureza, e o teor de metais alcalinos, metais de transi\u00e7\u00e3o, elementos Al e B \u00e9 um indicador chave de mat\u00e9rias-primas de quartzo de alta pureza. Os requisitos para o teor de elementos de impureza variam dependendo da finalidade do vidro de quartzo preparado, mas a tend\u00eancia geral \u00e9 que quanto menor, melhor.<\/p>\n\n\n\n

\"\"<\/a><\/figure>\n\n\n\n

Elemento de metal alcalino<\/h2>\n\n\n\n

Os elementos de metais alcalinos na areia de quartzo incluem principalmente elementos de l\u00edtio (Li), s\u00f3dio (Na) e pot\u00e1ssio (K). Esses elementos s\u00e3o facilmente difundidos e quimicamente ativos no quartzo, tornando-os relativamente f\u00e1ceis de remover. No entanto, eles representam grandes danos. Em altas temperaturas, esses elementos atuam como fluxos, causando fen\u00f4menos ruins, como perda de transpar\u00eancia e deforma\u00e7\u00e3o em alta temperatura em vidros de alta temperatura. Eles catalisam a cristaliza\u00e7\u00e3o, afetam a estabilidade t\u00e9rmica dos produtos de quartzo e tamb\u00e9m afetam as propriedades \u00f3pticas e t\u00e9rmicas do vidro de quartzo, reduzindo a vida \u00fatil dos semicondutores. O coeficiente diel\u00e9trico e a perda diel\u00e9trica do vidro de quartzo aumentar\u00e3o, enquanto a velocidade de propaga\u00e7\u00e3o e a resist\u00eancia mec\u00e2nica do a luz nos produtos de quartzo diminuir\u00e1.<\/p>\n\n\n\n

A redu\u00e7\u00e3o do conte\u00fado de elementos de metais alcalinos \u00e9 ben\u00e9fica para melhorar o ponto de amolecimento de cadinhos de quartzo de alta pureza, aumentando sua resist\u00eancia \u00e0 deforma\u00e7\u00e3o e melhorando o rendimento de monocristais. A areia padr\u00e3o IOTA requer um total de 2,4 elementos de metal alcalino \u00d7 10-6, o quartzo de alta pureza total necess\u00e1rio para cadinhos semicondutores usados para tubos de processo, processamento de wafer de sil\u00edcio, blocos de quartzo e extra\u00e7\u00e3o de sil\u00edcio monocristalino \u00e9 1,4 \u00d7 10-6, CZ os cadinhos requerem um total de 0,5 \u00d7 10-6, e o total necess\u00e1rio para areia de quartzo de pureza ultra-alta usada para pastilhas de sil\u00edcio de 12 polegadas ou maiores \u00e9 0,08 \u00d7 10-6.<\/p>\n\n\n\n

Elementos met\u00e1licos de transi\u00e7\u00e3o<\/h2>\n\n\n\n

Os elementos de metais de transi\u00e7\u00e3o dopados em areia de quartzo incluem principalmente ferro (Fe), zinco (Zn), cobre (Cu), cromo (Cr), mangan\u00eas (Mn), n\u00edquel (Ni) e outros elementos. Esses elementos t\u00eam um impacto significativo nos produtos de quartzo, e os oligoelementos podem se dissolver no sil\u00edcio fundido para evitar a condutividade, o que prejudica a previsibilidade e a confiabilidade do instrumento. O impacto objetivo nos produtos de quartzo \u00e9 produzir manchas coloridas ou causar descolora\u00e7\u00e3o em alta temperatura, reduzindo a transmit\u00e2ncia da luz.<\/p>\n\n\n\n

Em aplica\u00e7\u00f5es de fibra \u00f3ptica, pode causar micro irregularidades, aumentar a perda de fibra e at\u00e9 mesmo levar \u00e0 distor\u00e7\u00e3o do sinal. No entanto, em aplica\u00e7\u00f5es de semicondutores, o pequeno conte\u00fado de elementos de metais de transi\u00e7\u00e3o no produto pode promover o crescimento de cristais.<\/p>\n\n\n\n

Elemento de alum\u00ednio de boro<\/h2>\n\n\n\n

O teor do elemento boro (B) na areia de quartzo est\u00e1 diretamente relacionado \u00e0 geologia do min\u00e9rio de quartzo. Os \u00edons B podem entrar na estrutura das mol\u00e9culas de silicato e gerar fortes liga\u00e7\u00f5es qu\u00edmicas, e n\u00e3o apenas em minerais contendo boro. A quantidade excessiva do elemento B tem um impacto fatal na trefila\u00e7\u00e3o do sil\u00edcio monocristalino, e um elemento 1\u00d710-6 B pode reduzir significativamente a resist\u00eancia do sil\u00edcio monocristalino. Cadinhos de quartzo de alta pureza exigem altos requisitos para B, com um conte\u00fado de elemento inferior a 0,04 \u00d7 10-6.<\/p>\n\n\n\n

O elemento alum\u00ednio (Al) existe principalmente em minerais impuros, como feldspato, argila e mica na areia de quartzo. \u00c9 o elemento de impureza mais abundante na areia de quartzo, e o Al pode entrar na estrutura tetra\u00e9drica Si-O para substituir o sil\u00edcio, formando uma estrutura Al-O. Depois que Al3+ substitui Si4+, elementos de metais alcalinos ou mesmo elementos de metais de transi\u00e7\u00e3o s\u00e3o selecionados para compensar a carga e equilibrar a carga. O Al que entra no esqueleto de Si-O n\u00e3o ser\u00e1 facilmente removido. O Al tem pouco efeito nos semicondutores, mas tem um impacto significativo no vidro de quartzo usado em fontes de luz el\u00e9trica. Como a IA pode colorir produtos de quartzo sob certas condi\u00e7\u00f5es, ela afeta a transmit\u00e2ncia espectral e, portanto, afeta a efici\u00eancia da luz. A areia padr\u00e3o IOTA requer conte\u00fado de elemento Al (12-18) \u00d7 10-6.<\/p>\n\n\n\n

Elementos n\u00e3o met\u00e1licos<\/h2>\n\n\n\n

Os elementos n\u00e3o met\u00e1licos da areia de quartzo s\u00e3o compostos principalmente de oxig\u00eanio (O), hidrog\u00eanio (H), nitrog\u00eanio (N) e outros elementos. O principal corpo de oxig\u00eanio \u00e9 o SiO2, enquanto outros existem na forma de H2O, N2 e O2. A fratura das liga\u00e7\u00f5es Si-O no SiO2 resultar\u00e1 em defeitos que se combinam com OH ou H para formar grupos SiH ou SiOH. Os grupos hidroxila s\u00e3o defeitos de impureza e defeitos estruturais de rede.<\/p>\n\n\n\n

Os grupos hidroxila t\u00eam um impacto significativo nas propriedades do quartzo e do vidro de quartzo. Em primeiro lugar, a presen\u00e7a de grupos hidroxila reduz a estabilidade qu\u00edmica do quartzo. Em segundo lugar, os grupos hidroxila aumentam a porosidade da estrutura do quartzo, reduzem a densidade, diminuem a for\u00e7a de liga\u00e7\u00e3o e reduzem a velocidade de propaga\u00e7\u00e3o do som no vidro de quartzo. Os grupos hidroxila tamb\u00e9m podem reduzir a viscosidade do quartzo, e a presen\u00e7a de grupos hidroxila em baixas temperaturas pode causar uma diminui\u00e7\u00e3o mais significativa na viscosidade. Al\u00e9m disso, os grupos hidroxila tamb\u00e9m afetam a pureza dos produtos eletr\u00f4nicos, reduzem a temperatura de amolecimento do quartzo, promovem a precipita\u00e7\u00e3o de cristais, reduzem o \u00edndice de refra\u00e7\u00e3o do quartzo e afetam a uniformidade \u00f3ptica do vidro de quartzo.<\/p>","protected":false},"excerpt":{"rendered":"

Os elementos de impureza t\u00eam um impacto significativo na qualidade dos produtos de quartzo de alta pureza, e o teor de metais alcalinos, metais de transi\u00e7\u00e3o, elementos Al e B \u00e9 um indicador chave de [...]<\/p>","protected":false},"author":1,"featured_media":15674,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"default","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","ast-disable-related-posts":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center 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