{"id":15764,"date":"2024-04-16T08:03:29","date_gmt":"2024-04-16T08:03:29","guid":{"rendered":"http:\/\/quartz-grinding.com\/?p=15764"},"modified":"2024-04-16T08:03:32","modified_gmt":"2024-04-16T08:03:32","slug":"the-surface-modification-effect-of-silica-powder-will-determine-its-quality","status":"publish","type":"post","link":"https:\/\/www.quartz-grinding.com\/tr\/the-surface-modification-effect-of-silica-powder-will-determine-its-quality\/","title":{"rendered":"Silika tozunun y\u00fczey modifikasyon etkisi kalitesini belirleyecektir."},"content":{"rendered":"

Silika tozunun kendisi polar ve hidrofilik bir maddedir. Polimer matris ile farkl\u0131 aray\u00fcz \u00f6zelliklerine sahiptir ve uyumlulu\u011fu zay\u0131ft\u0131r. Temel malzemede da\u011f\u0131lmas\u0131 genellikle zordur. Bu nedenle silika tozunun y\u00fczey modifikasyonu genellikle gereklidir. Silika tozu y\u00fczeyinin fiziksel ve kimyasal \u00f6zelliklerini uygulaman\u0131n ihtiya\u00e7lar\u0131na g\u00f6re bilin\u00e7li olarak de\u011fi\u015ftirin, b\u00f6ylece organik polimer malzemelerle uyumlulu\u011funu geli\u015ftirin ve polimer malzemelerdeki da\u011f\u0131l\u0131m ve ak\u0131\u015fkanl\u0131k gereksinimlerini kar\u015f\u0131lay\u0131n.
\u200b
Silika tozunun hammadde kalitesi, modifikasyon prosesi, y\u00fczey modifikasyon y\u00f6ntemi ve modifiye edici, modifiye edici dozaj\u0131, modifikasyon proses ko\u015fullar\u0131 (modifikasyon s\u0131cakl\u0131\u011f\u0131, zaman, pH ve kar\u0131\u015ft\u0131rma h\u0131z\u0131) gibi fakt\u00f6rlerin t\u00fcm\u00fc silika tozunun y\u00fczey modifikasyon etkisini etkiler. Bunlar aras\u0131nda y\u00fczey modifikasyon y\u00f6ntemleri ve de\u011fi\u015ftiriciler, modifikasyon etkisini etkileyen ana fakt\u00f6rlerdir.<\/p>\n\n\n\n

\"kuvars
kuvars kumu<\/figcaption><\/figure>\n\n\n\n

Silika tozu hammadde kalitesi<\/h2>\n\n\n\n

Silika tozunun t\u00fcr\u00fc, par\u00e7ac\u0131k boyutu, spesifik y\u00fczey alan\u0131, y\u00fczey fonksiyonel gruplar\u0131 ve di\u011fer \u00f6zellikleri, y\u00fczey de\u011fi\u015ftiricilerle kombinasyonunu do\u011frudan etkiler. Farkl\u0131 silika tozu t\u00fcrlerinin modifikasyon etkileri de farkl\u0131d\u0131r. Bunlar aras\u0131nda, k\u00fcresel silika tozu iyi ak\u0131\u015fkanl\u0131\u011fa sahiptir, modifikasyon i\u015flemi s\u0131ras\u0131nda de\u011fi\u015ftirici ile birle\u015ftirilmesi kolayd\u0131r ve organik polimer sistemi i\u00e7inde daha iyi da\u011f\u0131labilir. Yo\u011funluk, sertlik, dielektrik sabiti ve di\u011fer \u00f6zellikler a\u00e7\u0131sal silika tozundan \u00f6nemli \u00f6l\u00e7\u00fcde daha iyidir.
\u200b
\u00d6rne\u011fin Huang Weizhuang ve ark. farkl\u0131 silika tozu t\u00fcrlerinin bak\u0131r kapl\u0131 laminatlar\u0131n \u0131s\u0131 direnci \u00fczerindeki etkilerini inceledi. Bak\u0131r kapl\u0131 laminatlar haz\u0131rlamak i\u00e7in dolgu maddesi olarak amorf silika tozu, yar\u0131 k\u00fcresel kristalin silika tozu ve k\u00fcresel erimi\u015f silika tozu kulland\u0131lar ve bak\u0131r kapl\u0131 laminatlar\u0131n termal direncini \u00f6l\u00e7t\u00fcler. Is\u0131 direnci ve aray\u00fczey \u00f6zellikleri. Sonu\u00e7lar k\u00fcresel silika tozunun epoksi re\u00e7ineyle daha iyi uyumlu oldu\u011funu ve haz\u0131rlanan bak\u0131r kapl\u0131 laminat\u0131n daha iyi \u0131s\u0131 direncine sahip oldu\u011funu g\u00f6stermektedir.
\u200b
Genel olarak silika tozunun par\u00e7ac\u0131k boyutu ne kadar k\u00fc\u00e7\u00fckse, spesifik y\u00fczey alan\u0131 da o kadar b\u00fcy\u00fck olur, y\u00fczeydeki aktif alanlar o kadar fazla olur ve kullan\u0131lan de\u011fi\u015ftirici miktar\u0131 da artar. Ek olarak, farkl\u0131 par\u00e7ac\u0131k boyutlar\u0131na sahip silika tozunun da uygulama prosesi s\u0131ras\u0131nda sonraki \u00fcr\u00fcnlerin performans\u0131 \u00fczerinde belirli bir etkisi vard\u0131r. \u00d6rne\u011fin silika tozunu re\u00e7ineyle kar\u0131\u015ft\u0131r\u0131rken par\u00e7ac\u0131k boyutu da\u011f\u0131l\u0131m\u0131 s\u0131k\u0131 bir \u015fekilde kontrol edilmeli ve \u00e7ok b\u00fcy\u00fck veya \u00e7ok k\u00fc\u00e7\u00fck olmamal\u0131d\u0131r. Par\u00e7ac\u0131k boyutu \u00e7ok b\u00fcy\u00fckse dolgu uygulama performans\u0131 zay\u0131flayacak, par\u00e7ac\u0131k boyutu \u00e7ok k\u00fc\u00e7\u00fckse re\u00e7ine sisteminin viskozitesi artacak ve ak\u0131\u015fkanl\u0131\u011f\u0131 bozulacakt\u0131r. .<\/p>\n\n\n\n

Y\u00fczey modifikasyon y\u00f6ntemleri ve de\u011fi\u015ftiriciler<\/h2>\n\n\n\n

\u015eu anda silika tozunun y\u00fczey modifikasyon y\u00f6ntemleri temel olarak organik modifikasyon, inorganik modifikasyon ve mekanokimyasal modifikasyondur; bunlar\u0131n aras\u0131nda en yayg\u0131n kullan\u0131lan modifikasyon y\u00f6ntemi organik modifikasyondur. Tek modifikasyonun etkisi iyi olmad\u0131\u011f\u0131nda, kompozit modifikasyon i\u00e7in organik modifikasyonu di\u011fer modifikasyon y\u00f6ntemleriyle birle\u015ftirmeyi d\u00fc\u015f\u00fcnebilirsiniz.<\/p>\n\n\n\n

Organik modifikasyon<\/h3>\n\n\n\n

Organik modifikasyon, silika tozunun y\u00fczey \u00f6zelliklerini de\u011fi\u015ftirmek i\u00e7in silika tozunun y\u00fczeyinde fiziksel adsorpsiyon, kimyasal adsorpsiyon ve kimyasal reaksiyonlar\u0131 ger\u00e7ekle\u015ftirmek i\u00e7in organik maddedeki fonksiyonel gruplar\u0131 kullanan bir y\u00f6ntemdir. \u015eu anda en yayg\u0131n olarak kullan\u0131lan organik de\u011fi\u015ftiriciler, esas olarak amino, epoksi, vinil, s\u00fclf\u00fcr ve di\u011fer t\u00fcrleri i\u00e7eren silan birle\u015ftirme maddeleridir. Modifikasyon etkisi genellikle iyidir ancak fiyat\u0131 pahal\u0131d\u0131r. Baz\u0131 ara\u015ft\u0131rmac\u0131lar silika tozunu de\u011fi\u015ftirmek i\u00e7in al\u00fcminat, titanat ve stearik asit gibi nispeten ucuz de\u011fi\u015ftiriciler kullan\u0131yor ancak modifikasyon etkisi genellikle silan birle\u015ftirme maddelerininki kadar iyi de\u011fil. Bu nedenle, ekonomik faydalar ile modifikasyon etkilerinin birle\u015ftirilmesi, silika tozunu kompozit olarak modifiye etmek i\u00e7in iki veya daha fazla y\u00fczey de\u011fi\u015ftirici kullan\u0131ld\u0131\u011f\u0131nda, modifikasyon etkisi genellikle tek bir de\u011fi\u015ftiricinin kullan\u0131lmas\u0131ndan daha idealdir.<\/p>\n\n\n\n

\u0130norganik modifikasyon<\/h3>\n\n\n\n

\u0130norganik modifikasyon, malzemeye yeni i\u015flevler kazand\u0131rmak i\u00e7in silika tozunun y\u00fczeyindeki metallerin, inorganik oksitlerin, hidroksitlerin vb. kaplanmas\u0131 veya birle\u015ftirilmesi anlam\u0131na gelir. \u00d6rne\u011fin, Oyama ve ark. SiO2 y\u00fczeyini Al(OH)3 ile kaplamak i\u00e7in bir \u00e7\u00f6keltme y\u00f6ntemi kullanm\u0131\u015f ve daha sonra baz\u0131 \u00f6zel uygulama gereksinimlerini kar\u015f\u0131lamak i\u00e7in de\u011fi\u015ftirilmi\u015f SiO2'yi polidivinilbenzen ile sarm\u0131\u015ft\u0131r.<\/p>\n\n\n\n

Mekanokimyasal modifikasyon<\/h3>\n\n\n\n

Mekanokimyasal modifikasyon, silika tozunun y\u00fczeyindeki aktif noktalar\u0131 veya aktif gruplar\u0131 artt\u0131rmak i\u00e7in toz par\u00e7ac\u0131klar\u0131n\u0131n y\u00fczeyini aktive etmek i\u00e7in ilk \u00f6nce ultra ince \u00f6\u011f\u00fctme ve di\u011fer g\u00fc\u00e7l\u00fc mekanik kuvvetlerin kullan\u0131lmas\u0131n\u0131 ve ard\u0131ndan silika tozunun kompozit modifikasyonunu elde etmek i\u00e7in de\u011fi\u015ftiricilerin birle\u015ftirilmesini ifade eder.<\/p>\n\n\n\n

De\u011fi\u015ftirici dozaj\u0131<\/h2>\n\n\n\n

Modifiye edici madde miktar\u0131 genellikle silika tozunun y\u00fczeyindeki aktif noktalar\u0131n (Si-OH gibi) say\u0131s\u0131 ve y\u00fczeyi kaplayan modifiye edicinin monomolek\u00fcler tabakas\u0131 ve bimolek\u00fcler kal\u0131nl\u0131\u011f\u0131 ile ili\u015fkilidir. De\u011fi\u015ftirici miktar\u0131 \u00e7ok k\u00fc\u00e7\u00fck oldu\u011funda, de\u011fi\u015ftirilmi\u015f silika tozunun y\u00fczeyinin aktivasyon derecesi y\u00fcksek olmayacakt\u0131r; De\u011fi\u015ftirici miktar\u0131 \u00e7ok b\u00fcy\u00fck oldu\u011funda, yaln\u0131zca modifikasyon maliyetini art\u0131rmakla kalmayacak, ayn\u0131 zamanda modifiye silika tozunun y\u00fczeyinde \u00e7ok katmanl\u0131 bir fiziksel katman olu\u015fturacakt\u0131r. Adsorpsiyon, silika tozu ile organik polimer aras\u0131ndaki aray\u00fcz\u00fcn zay\u0131f bir tabaka olu\u015fturmas\u0131na neden olur ve bu da tek molek\u00fcll\u00fc bir k\u00f6pr\u00fc olarak i\u015flev g\u00f6rememesine neden olur.<\/p>\n\n\n\n

Modifikasyon s\u00fcreci ve durum optimizasyonu<\/h2>\n\n\n\n

Silika tozu i\u00e7in yayg\u0131n olarak kullan\u0131lan modifikasyon i\u015flemleri esas olarak kuru modifikasyonu, \u0131slak modifikasyonu ve kompozit modifikasyonu i\u00e7erir.<\/p>\n\n\n\n

(1) Kuru modifikasyon, silika tozunun modifikasyon ekipman\u0131nda nispeten kuru bir durumda da\u011f\u0131t\u0131ld\u0131\u011f\u0131 ve belirli bir s\u0131cakl\u0131kta belirli bir miktarda y\u00fczey de\u011fi\u015ftirici ile birle\u015ftirildi\u011fi bir modifikasyondur. Kuru modifikasyon i\u015flemi basittir ve \u00fcretim maliyeti d\u00fc\u015f\u00fckt\u00fcr. \u015eu anda yerli silika tozunun y\u00fczey modifikasyonunun ana y\u00f6ntemidir ve mikron d\u00fczeyindeki silika tozu i\u00e7in uygundur.
\u200b
(2) Islak modifikasyon, y\u00fczeyin ba\u011flanma enerjisini azaltmak i\u00e7in silikon tozunun y\u00fczeyinin s\u0131v\u0131 faz ko\u015fullar\u0131 alt\u0131nda \u0131slat\u0131lmas\u0131 ve daha sonra silikon Y\u00fczey elde etmek i\u00e7in belirli bir miktarda y\u00fczey de\u011fi\u015ftiriciler ve katk\u0131 maddeleri eklenmesi, belirli bir s\u0131cakl\u0131kta kar\u0131\u015ft\u0131r\u0131lmas\u0131 ve da\u011f\u0131t\u0131lmas\u0131 anlam\u0131na gelir. Mikrotozlar\u0131n modifikasyonu. Islak modifikasyon i\u015flemi, silika tozunun ve de\u011fi\u015ftiricinin daha kolay da\u011f\u0131lmas\u0131n\u0131 ve daha tam olarak birle\u015ftirilmesini sa\u011flayarak modifikasyonu daha d\u00fczg\u00fcn hale getirebilir. Bununla birlikte, daha sonraki dehidrasyon i\u015flemleri gereklidir, s\u00fcre\u00e7 karma\u015f\u0131kt\u0131r ve enerji t\u00fcketimi y\u00fcksektir ve par\u00e7ac\u0131k boyutu 5 \u03bcm'den k\u00fc\u00e7\u00fck olan ultra ince par\u00e7ac\u0131klar i\u00e7in daha uygundur. Silika tozu modifikasyonu. Ek olarak, \u0131slak modifikasyon i\u015flemi s\u0131ras\u0131nda de\u011fi\u015ftiricinin suda \u00e7\u00f6z\u00fcn\u00fcrl\u00fc\u011f\u00fc de dikkate al\u0131nmal\u0131d\u0131r, \u00e7\u00fcnk\u00fc yaln\u0131zca suda daha iyi \u00e7\u00f6z\u00fcn\u00fcrl\u00fc\u011fe sahip de\u011fi\u015ftiriciler, silika tozunun y\u00fczeyindeki Si-OH gruplar\u0131yla daha iyi da\u011f\u0131labilir ve etkile\u015fime girebilir.
\u200b
(3) Kompozit modifikasyon, silika tozunun aktivasyon derecesini daha da geli\u015ftirmek i\u00e7in kuru ve \u0131slak modifikasyon i\u015flemlerinin kombinasyonunu ifade eder. \u00d6rne\u011fin Cao Jiakai ve ark. modifikasyonu kuru ve \u0131slak i\u015flemlerle iki a\u015famada ger\u00e7ekle\u015ftirdi. Yani, silika tozunun \u00f6n modifikasyonunu ger\u00e7ekle\u015ftirmek i\u00e7in ilk \u00f6nce kuru modifikasyon yoluyla y-(2,3-epoksipropoksi)propiltrimetilsilan kullan\u0131ld\u0131. Aktif silika mikro tozu elde etmek i\u00e7in modifikasyon i\u00e7in N-fenil-aminotrimetoksisilan kullan\u0131larak modifikasyon ve daha sonra \u0131slak modifikasyon yoluyla. Sonu\u00e7lar, kompozit modifikasyon i\u015flemiyle \u00fcretilen silika tozunun y\u00fcksek aktiviteye, iyi hidrofobikli\u011fe, az say\u0131da y\u00fczey hidroksil grubuna sahip oldu\u011funu ve re\u00e7ine sisteminde daha iyi da\u011f\u0131labilece\u011fini g\u00f6stermektedir.
\u200b
Ayr\u0131ca silika tozunun iyi bir modifikasyon etkisi elde etmek i\u00e7in modifikasyon i\u015flemi s\u0131ras\u0131nda s\u0131cakl\u0131k, pH, s\u00fcre, kar\u0131\u015ft\u0131rma h\u0131z\u0131 ve di\u011fer i\u015flem ko\u015fullar\u0131 kontrol edilmelidir.
\u200b
Modifikasyon s\u0131cakl\u0131\u011f\u0131, modifiye edici ile silika tozu aras\u0131nda yo\u011funla\u015fma, dehidrasyon ve g\u00fc\u00e7l\u00fc kovalent ba\u011flar\u0131n olu\u015fumu i\u00e7in \u00f6nemli bir ko\u015fuldur. Modifikasyon s\u0131cakl\u0131\u011f\u0131 \u00e7ok y\u00fcksek veya \u00e7ok d\u00fc\u015f\u00fck olmamal\u0131d\u0131r. \u00c7ok y\u00fcksek bir s\u0131cakl\u0131k, de\u011fi\u015ftiricinin ayr\u0131\u015fmas\u0131na veya buharla\u015fmas\u0131na neden olur ve \u00e7ok d\u00fc\u015f\u00fck bir s\u0131cakl\u0131k, de\u011fi\u015ftiricinin ayr\u0131\u015fmas\u0131na veya buharla\u015fmas\u0131na neden olur. Bu, de\u011fi\u015ftirici ile silika tozu aras\u0131ndaki reaksiyon h\u0131z\u0131n\u0131 azaltarak modifikasyon etkisini etkileyecektir.<\/p>\n\n\n\n

\u00c7\u00f6z\u00fcc\u00fclerde \u00e7\u00f6z\u00fcnen de\u011fi\u015ftiriciler i\u00e7in pH, hidroliz etkisini etkileyecektir. Daha uzun bir modifikasyon s\u00fcresi, de\u011fi\u015ftirici ile silika tozu aras\u0131ndaki etkile\u015fimi daha eksiksiz ve sa\u011flam hale getirir; uygun bir kar\u0131\u015ft\u0131rma h\u0131z\u0131, de\u011fi\u015ftiricinin ve silika tozunun daha tam olarak temas etmesini sa\u011flayabilir ve de\u011fi\u015ftiricinin silika tozu i\u00e7indeki da\u011f\u0131l\u0131m\u0131n\u0131 geli\u015ftirebilir.<\/p>","protected":false},"excerpt":{"rendered":"

Silika tozunun kendisi polar ve hidrofilik bir maddedir. Polimer matris ile farkl\u0131 aray\u00fcz \u00f6zelliklerine sahiptir ve uyumlulu\u011fu zay\u0131ft\u0131r. Ortal\u0131kta da\u011f\u0131lmak genellikle zordur [\u2026]<\/p>","protected":false},"author":1,"featured_media":15766,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"default","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","ast-disable-related-posts":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"set","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"footnotes":""},"categories":[42],"tags":[],"class_list":["post-15764","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-industry-news"],"yoast_head":"\nThe surface modification effect of silica powder will determine its quality - Silica powder (ultrafine quartz powder) processing expert<\/title>\n<meta name=\"description\" content=\"Silica powder itself is a polar and hydrophilic substance. It has different interface properties with the polymer matrix and has poor compatibility.\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/www.quartz-grinding.com\/tr\/the-surface-modification-effect-of-silica-powder-will-determine-its-quality\/\" \/>\n<meta property=\"og:locale\" content=\"tr_TR\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"The surface modification effect of silica powder will determine its quality - Silica powder (ultrafine quartz powder) processing expert\" \/>\n<meta property=\"og:description\" content=\"Silica powder itself is a polar and hydrophilic substance. 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