{"id":15836,"date":"2024-10-16T01:53:32","date_gmt":"2024-10-16T01:53:32","guid":{"rendered":"http:\/\/quartz-grinding.com\/?p=15836"},"modified":"2024-10-18T05:03:56","modified_gmt":"2024-10-18T05:03:56","slug":"silicon-after-grinding-by-mill-can-be-used-in-negative-electrode","status":"publish","type":"post","link":"https:\/\/www.quartz-grinding.com\/tr\/silicon-after-grinding-by-mill-can-be-used-in-negative-electrode\/","title":{"rendered":"\u00d6\u011f\u00fctme De\u011firmeninde \u0130\u015flenen Silisyum Negatif Elektrotta Kullan\u0131labilir"},"content":{"rendered":"

Pil teknolojisinin h\u0131zla geli\u015fmesiyle birlikte, silikon<\/a> kademeli olarak potansiyel negatif elektrot malzemesi haline gelir. 1970'lerin ba\u015flar\u0131nda, insanlar elektrokimyasal reaksiyonu ke\u015ffettiler lityum (Li)<\/a> ve elementel silisyum (Si). \u00d6\u011f\u00fctme de\u011firmeni, \u00f6rne\u011fin bilyal\u0131 de\u011firmen ile i\u015fleme yoluyla, silisyum pilin negatif elektrotunda iyi kullan\u0131labilir. <\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

Lityum-silikon ala\u015f\u0131m\u0131n\u0131n (LixSi, 0 < x \u2264 4.4) reaksiyon potansiyeli, lityumlama derecesinin artmas\u0131yla azal\u0131r. M\u00fckemmel \u00f6zellikleri nedeniyle, silisyum, yeni nesil negatif elektrot malzemeleri olarak akademi ve end\u00fcstri taraf\u0131ndan yo\u011fun ilgi g\u00f6rm\u00fc\u015ft\u00fcr. Ancak, saf silisyum veya y\u00fcksek i\u00e7erikli silisyumu do\u011frudan pilin negatif elektrodu olarak kullanamay\u0131z. Neden? A\u015fa\u011f\u0131da analiz edelim:<\/p>\n\n\n\n

Saf silisyum veya y\u00fcksek safl\u0131ktaki silisyumun negatif elektrot olarak kullan\u0131lamamas\u0131n\u0131n nedenleri<\/strong><\/h2>\n\n\n\n

 1. Hacim geni\u015flemesi sorunu<\/strong><\/h3>\n\n\n\n

Silikonun hacmi tamamen lityumland\u0131\u011f\u0131nda 280%'den fazla de\u011fi\u015fir. Lityum yerle\u015ftirme i\u015flemi, s\u00f6nm\u00fc\u015f bir \u015fi\u015feye hava \u00fcflemek gibidir balon<\/a>. Gaz i\u00e7eri\u011fi artt\u0131k\u00e7a balon geni\u015flemeye devam eder. Lityum iyonlar\u0131n\u0131n uzakla\u015ft\u0131r\u0131lmas\u0131 i\u015flemi bir balonun s\u00f6nd\u00fcr\u00fclmesine benzer ve hacim orijinal boyutuna geri d\u00f6ner.<\/p>\n\n\n\n

Ancak, kat\u0131 par\u00e7ac\u0131k olarak silikon, bir balon gibi iyi elastik deformasyona sahip de\u011fildir. S\u00fcrekli genle\u015fme ve b\u00fcz\u00fclme ile silikon par\u00e7ac\u0131klar\u0131n\u0131n, anot malzemesinin ve elektrot tabakas\u0131n\u0131n ciddi \u015fekilde \u00e7atlamas\u0131na ve toz haline gelmesine neden olma olas\u0131l\u0131\u011f\u0131 \u00e7ok y\u00fcksektir. Bu durumda, anot malzemesi ile elektrolit aras\u0131nda yeni bir aray\u00fcz olu\u015facak ve bu, elektrolit t\u00fcketimi ve SEI kal\u0131nl\u0131\u011f\u0131 \u00fczerinde olumsuz bir etkiye neden olacakt\u0131r.<\/p>\n\n\n\n

2.Elektriksel iletkenlik sorunu <\/strong><\/h3>\n\n\n\n

Y\u00fcksek safl\u0131ktaki silisyumun (< 10) elektronik iletkenli\u011fi-5<\/sup> S\/cm) ve lityum iyonlar\u0131n\u0131n silisyum i\u00e7indeki dif\u00fczyon h\u0131z\u0131 (10\u221214<\/sup>\u201410\u221213<\/sup> santimetre2<\/sup>\/s) grafitten \u00e7ok daha d\u00fc\u015f\u00fckt\u00fcr. Elektronik iletkenlik, anot malzemesindeki elektron iletimini etkiler, bu nedenle iyi bir iletken a\u011f son derece \u00f6nemlidir. Dahas\u0131, iyonik iletkenlik, lityum iyonlar\u0131n\u0131n g\u00f6m\u00fclmesi ve \u00e7\u0131kar\u0131lmas\u0131 s\u00fcrecini etkiler ve iletim mesafesini k\u0131salt\u0131r.<\/p>\n\n\n\n

Peki, bu sorunu nas\u0131l \u00e7\u00f6zebiliriz? Cevap, silikon ve grafiti birle\u015ftirmektir. <\/strong><\/h2>\n\n\n\n

Silisyum malzemeye grafit eklemek, integral kompozit elektrodun hacim de\u011fi\u015fimini tamponlayabilir. D\u00fc\u015f\u00fck silisyum i\u00e7eri\u011fi (yakla\u015f\u0131k 20%) ko\u015fulu alt\u0131nda, kat\u0131 elektrolit aray\u00fcz\u00fcn\u00fcn (SEI) olu\u015fumu i\u00e7in ana reaksiyon alanlar\u0131 grafit par\u00e7ac\u0131klar\u0131 taraf\u0131ndan sa\u011flan\u0131r. Silisyuma grafit eklemek, elektrodun dif\u00fczivitesini iyile\u015ftirebilir ve elektrot \u00fcretiminde i\u015flenebilirli\u011fi iyile\u015ftirebilir, b\u00f6ylece daha y\u00fcksek enerji yo\u011funlu\u011fu elde edilebilir.<\/p>\n\n\n\n

\u00d6\u011f\u00fctme de\u011firmeni ile i\u015flenen silisyumun ak\u00fc negatif elektrotunda uygulama olas\u0131l\u0131\u011f\u0131<\/strong><\/h2>\n\n\n\n

Y\u00fcksek teorik \u00f6zg\u00fcl kapasite ve enerji yo\u011funlu\u011fu nedeniyle, silikon pilin performans\u0131n\u0131 \u00f6nemli \u00f6l\u00e7\u00fcde iyile\u015ftirebilir. Karbon kaplamal\u0131 silikon oksit, nano silikon karbon, silikon nano tel ve amorf silikon ala\u015f\u0131m\u0131 gibi silikon bazl\u0131 negatif elektrot malzemeleri, art\u0131k g\u00fc\u00e7 pili, enerji depolama pili ve t\u00fcketici pili alanlar\u0131nda geni\u015f bir uygulamaya sahiptir. Gelecekte, silikon bazl\u0131 negatif elektrot malzemesi pil end\u00fcstrisinin odak noktas\u0131 haline gelecek ve b\u00fcy\u00fck \u00f6l\u00e7ekli ticari uygulama elde edecektir.<\/p>\n\n\n\n

Pil negatif elektrot malzemelerinde kullan\u0131lan silikon esas olarak nano formdad\u0131r, nano silikon g\u00fcc\u00fcn\u00fc \u00f6\u011f\u00fctme de\u011firmeni yoluyla elde edebiliriz, \u00f6rne\u011fin: bilyal\u0131 de\u011firmen<\/strong>.<\/a> Ayn\u0131 zamanda, silikon negatif elektrot malzemesinin elektrokimyasal performans\u0131n\u0131 iyile\u015ftirmek i\u00e7in silionun modifikasyonu gereklidir. Profesyonel bir toz ekipman \u00fcreticisi olarak, Qingdao Epic Toz Makineleri Co., Ltd<\/em><\/strong><\/em><\/strong>.<\/a> \u00fcretebilir bilyal\u0131 de\u011firmen ve y\u00fczey kaplama modifikasyon sistemi<\/strong> silikon i\u015fleme i\u00e7in. \u0130lgili herhangi bir ihtiyac\u0131n\u0131z ve sorunuz varsa l\u00fctfen ileti\u015fime ge\u00e7in Qingdao Destan\u0131<\/a><\/strong>.<\/p>\n\n\n\n

A\u015fa\u011f\u0131da referans olmas\u0131 a\u00e7\u0131s\u0131ndan foto\u011fraflar bulunmaktad\u0131r.<\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n
\"\"<\/figure>","protected":false},"excerpt":{"rendered":"

Pil teknolojisinin h\u0131zla geli\u015fmesiyle birlikte, silikon giderek potansiyel bir negatif elektrot malzemesi haline geliyor. 1970'lerin ba\u015flar\u0131nda, insanlar lityum (Li) ve elementel silikon aras\u0131ndaki elektrokimyasal reaksiyonu ke\u015ffettiler [\u2026]<\/p>","protected":false},"author":1,"featured_media":15865,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"default","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","ast-disable-related-posts":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"set","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center 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