{"id":15836,"date":"2024-10-16T01:53:32","date_gmt":"2024-10-16T01:53:32","guid":{"rendered":"http:\/\/quartz-grinding.com\/?p=15836"},"modified":"2024-10-18T05:03:56","modified_gmt":"2024-10-18T05:03:56","slug":"silicon-after-grinding-by-mill-can-be-used-in-negative-electrode","status":"publish","type":"post","link":"https:\/\/www.quartz-grinding.com\/vi\/silicon-after-grinding-by-mill-can-be-used-in-negative-electrode\/","title":{"rendered":"Silic \u0111\u01b0\u1ee3c x\u1eed l\u00fd qua m\u00e1y nghi\u1ec1n c\u00f3 th\u1ec3 \u0111\u01b0\u1ee3c s\u1eed d\u1ee5ng trong \u0111i\u1ec7n c\u1ef1c \u00e2m"},"content":{"rendered":"

V\u1edbi s\u1ef1 ph\u00e1t tri\u1ec3n nhanh ch\u00f3ng c\u1ee7a c\u00f4ng ngh\u1ec7 pin, silic<\/a> d\u1ea7n d\u1ea7n tr\u1edf th\u00e0nh v\u1eadt li\u1ec7u \u0111i\u1ec7n c\u1ef1c \u00e2m ti\u1ec1m n\u0103ng. Ngay t\u1eeb nh\u1eefng n\u0103m 1970, ng\u01b0\u1eddi ta \u0111\u00e3 ph\u00e1t hi\u1ec7n ra ph\u1ea3n \u1ee9ng \u0111i\u1ec7n h\u00f3a gi\u1eefa liti (Li)<\/a> v\u00e0 silic nguy\u00ean t\u1ed1 (Si). Th\u00f4ng qua qu\u00e1 tr\u00ecnh x\u1eed l\u00fd b\u1eb1ng m\u00e1y nghi\u1ec1n, v\u00ed d\u1ee5: m\u00e1y nghi\u1ec1n bi, silic c\u00f3 th\u1ec3 \u0111\u01b0\u1ee3c s\u1eed d\u1ee5ng t\u1ed1t trong \u0111i\u1ec7n c\u1ef1c \u00e2m c\u1ee7a pin. <\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

\u0110i\u1ec7n th\u1ebf ph\u1ea3n \u1ee9ng c\u1ee7a h\u1ee3p kim lithium-silicon (LixSi, 0 < x \u2264 4,4) gi\u1ea3m khi m\u1ee9c \u0111\u1ed9 liti h\u00f3a t\u0103ng. Do c\u00e1c t\u00ednh ch\u1ea5t tuy\u1ec7t v\u1eddi c\u1ee7a n\u00f3, silicon \u0111\u00e3 thu h\u00fat s\u1ef1 ch\u00fa \u00fd r\u1ed9ng r\u00e3i t\u1eeb gi\u1edbi h\u1ecdc thu\u1eadt v\u00e0 c\u00f4ng nghi\u1ec7p nh\u01b0 l\u00e0 th\u1ebf h\u1ec7 v\u1eadt li\u1ec7u \u0111i\u1ec7n c\u1ef1c \u00e2m ti\u1ebfp theo. Tuy nhi\u00ean, ch\u00fang ta kh\u00f4ng th\u1ec3 s\u1eed d\u1ee5ng silicon nguy\u00ean ch\u1ea5t ho\u1eb7c silicon c\u00f3 h\u00e0m l\u01b0\u1ee3ng cao l\u00e0m \u0111i\u1ec7n c\u1ef1c \u00e2m c\u1ee7a pin tr\u1ef1c ti\u1ebfp. T\u1ea1i sao? Ch\u00fang ta h\u00e3y ph\u00e2n t\u00edch b\u00ean d\u01b0\u1edbi:<\/p>\n\n\n\n

L\u00fd do t\u1ea1i sao silicon nguy\u00ean ch\u1ea5t ho\u1eb7c silicon c\u00f3 \u0111\u1ed9 tinh khi\u1ebft cao kh\u00f4ng th\u1ec3 \u0111\u01b0\u1ee3c s\u1eed d\u1ee5ng l\u00e0m \u0111i\u1ec7n c\u1ef1c \u00e2m<\/strong><\/h2>\n\n\n\n

 1. V\u1ea5n \u0111\u1ec1 m\u1edf r\u1ed9ng th\u1ec3 t\u00edch<\/strong><\/h3>\n\n\n\n

Th\u1ec3 t\u00edch c\u1ee7a silicon thay \u0111\u1ed5i h\u01a1n 280% khi n\u00f3 \u0111\u01b0\u1ee3c liti h\u00f3a ho\u00e0n to\u00e0n. Qu\u00e1 tr\u00ecnh ch\u00e8n lithium gi\u1ed1ng nh\u01b0 th\u1ed5i kh\u00f4ng kh\u00ed v\u00e0o m\u1ed9t c\u00e1i x\u00ec h\u01a1i b\u00f3ng bay<\/a>. Khi h\u00e0m l\u01b0\u1ee3ng kh\u00ed t\u0103ng l\u00ean, qu\u1ea3 b\u00f3ng ti\u1ebfp t\u1ee5c gi\u00e3n n\u1edf. Trong khi qu\u00e1 tr\u00ecnh lo\u1ea1i b\u1ecf ion lithium gi\u1ed1ng nh\u01b0 vi\u1ec7c x\u00ec h\u01a1i c\u1ee7a qu\u1ea3 b\u00f3ng, v\u00e0 th\u1ec3 t\u00edch tr\u1edf l\u1ea1i k\u00edch th\u01b0\u1edbc ban \u0111\u1ea7u.<\/p>\n\n\n\n

Tuy nhi\u00ean, l\u00e0 h\u1ea1t r\u1eafn, silicon kh\u00f4ng c\u00f3 kh\u1ea3 n\u0103ng bi\u1ebfn d\u1ea1ng \u0111\u00e0n h\u1ed3i t\u1ed1t nh\u01b0 b\u00f3ng bay. C\u00e1c h\u1ea1t silicon, v\u1edbi s\u1ef1 gi\u00e3n n\u1edf v\u00e0 co l\u1ea1i li\u00ean t\u1ee5c, r\u1ea5t c\u00f3 th\u1ec3 g\u00e2y ra n\u1ee9t nghi\u00eam tr\u1ecdng v\u00e0 nghi\u1ec1n n\u00e1t v\u1eadt li\u1ec7u anode v\u00e0 l\u1edbp \u0111i\u1ec7n c\u1ef1c. Trong t\u00ecnh hu\u1ed1ng n\u00e0y, m\u1ed9t giao di\u1ec7n m\u1edbi gi\u1eefa v\u1eadt li\u1ec7u anode v\u00e0 ch\u1ea5t \u0111i\u1ec7n ph\u00e2n s\u1ebd \u0111\u01b0\u1ee3c h\u00ecnh th\u00e0nh v\u00e0 s\u1ebd d\u1eabn \u0111\u1ebfn t\u00e1c \u0111\u1ed9ng ti\u00eau c\u1ef1c \u0111\u1ebfn m\u1ee9c ti\u00eau th\u1ee5 ch\u1ea5t \u0111i\u1ec7n ph\u00e2n v\u00e0 \u0111\u1ed9 d\u00e0y SEI.<\/p>\n\n\n\n

2.V\u1ea5n \u0111\u1ec1 v\u1ec1 \u0111\u1ed9 d\u1eabn \u0111i\u1ec7n <\/strong><\/h3>\n\n\n\n

\u0110\u1ed9 d\u1eabn \u0111i\u1ec7n t\u1eed c\u1ee7a silicon c\u00f3 \u0111\u1ed9 tinh khi\u1ebft cao (< 10\u22125<\/sup> S\/cm) v\u00e0 t\u1ed1c \u0111\u1ed9 khu\u1ebfch t\u00e1n c\u1ee7a c\u00e1c ion lithium trong silicon (10\u221214<\/sup>\u201410\u221213<\/sup> cm2<\/sup>\/s) th\u1ea5p h\u01a1n nhi\u1ec1u so v\u1edbi graphite. \u0110\u1ed9 d\u1eabn \u0111i\u1ec7n t\u1eed s\u1ebd \u1ea3nh h\u01b0\u1edfng \u0111\u1ebfn qu\u00e1 tr\u00ecnh truy\u1ec1n electron trong v\u1eadt li\u1ec7u anode, do \u0111\u00f3, m\u1ea1ng l\u01b0\u1edbi d\u1eabn \u0111i\u1ec7n t\u1ed1t l\u00e0 v\u00f4 c\u00f9ng quan tr\u1ecdng. H\u01a1n n\u1eefa, \u0111\u1ed9 d\u1eabn ion s\u1ebd \u1ea3nh h\u01b0\u1edfng \u0111\u1ebfn qu\u00e1 tr\u00ecnh nh\u00fang v\u00e0 tr\u00edch xu\u1ea5t ion lithium v\u00e0 r\u00fat ng\u1eafn kho\u1ea3ng c\u00e1ch truy\u1ec1n.<\/p>\n\n\n\n

V\u1eady, l\u00e0m th\u1ebf n\u00e0o \u0111\u1ec3 gi\u1ea3i quy\u1ebft v\u1ea5n \u0111\u1ec1 n\u00e0y? C\u00e2u tr\u1ea3 l\u1eddi l\u00e0 k\u1ebft h\u1ee3p silicon v\u00e0 than ch\u00ec. <\/strong><\/h2>\n\n\n\n

Th\u00eam than ch\u00ec v\u00e0o v\u1eadt li\u1ec7u silicon c\u00f3 th\u1ec3 \u0111\u1ec7m s\u1ef1 thay \u0111\u1ed5i th\u1ec3 t\u00edch c\u1ee7a \u0111i\u1ec7n c\u1ef1c t\u1ed5ng h\u1ee3p t\u00edch h\u1ee3p. Trong \u0111i\u1ec1u ki\u1ec7n h\u00e0m l\u01b0\u1ee3ng silicon th\u1ea5p (kho\u1ea3ng 20%), c\u00e1c v\u1ecb tr\u00ed ph\u1ea3n \u1ee9ng ch\u00ednh \u0111\u1ec3 h\u00ecnh th\u00e0nh giao di\u1ec7n ch\u1ea5t \u0111i\u1ec7n ph\u00e2n r\u1eafn (SEI) \u0111\u01b0\u1ee3c cung c\u1ea5p b\u1edfi c\u00e1c h\u1ea1t than ch\u00ec. Th\u00eam than ch\u00ec v\u00e0o silicon c\u00f3 th\u1ec3 c\u1ea3i thi\u1ec7n kh\u1ea3 n\u0103ng khu\u1ebfch t\u00e1n c\u1ee7a \u0111i\u1ec7n c\u1ef1c v\u00e0 c\u1ea3i thi\u1ec7n kh\u1ea3 n\u0103ng gia c\u00f4ng trong s\u1ea3n xu\u1ea5t \u0111i\u1ec7n c\u1ef1c, do \u0111\u00f3 s\u1ebd thu \u0111\u01b0\u1ee3c m\u1eadt \u0111\u1ed9 n\u0103ng l\u01b0\u1ee3ng cao h\u01a1n.<\/p>\n\n\n\n

Tri\u1ec3n v\u1ecdng \u1ee9ng d\u1ee5ng c\u1ee7a silic \u0111\u01b0\u1ee3c x\u1eed l\u00fd b\u1eb1ng m\u00e1y nghi\u1ec1n trong \u0111i\u1ec7n c\u1ef1c \u00e2m c\u1ee7a pin<\/strong><\/h2>\n\n\n\n

Do c\u00f3 m\u1eadt \u0111\u1ed9 n\u0103ng l\u01b0\u1ee3ng v\u00e0 dung l\u01b0\u1ee3ng ri\u00eang l\u00fd thuy\u1ebft cao, silicon c\u00f3 th\u1ec3 c\u1ea3i thi\u1ec7n \u0111\u00e1ng k\u1ec3 hi\u1ec7u su\u1ea5t c\u1ee7a pin. V\u1eadt li\u1ec7u \u0111i\u1ec7n c\u1ef1c \u00e2m g\u1ed1c silicon, ch\u1eb3ng h\u1ea1n nh\u01b0 oxit silicon ph\u1ee7 carbon, nano silicon carbon, d\u00e2y nano silicon v\u00e0 h\u1ee3p kim silicon v\u00f4 \u0111\u1ecbnh h\u00ecnh, hi\u1ec7n c\u00f3 \u1ee9ng d\u1ee5ng r\u1ed9ng r\u00e3i trong c\u00e1c l\u0129nh v\u1ef1c pin \u0111i\u1ec7n, pin l\u01b0u tr\u1eef n\u0103ng l\u01b0\u1ee3ng v\u00e0 pin ti\u00eau d\u00f9ng. Trong t\u01b0\u01a1ng lai, v\u1eadt li\u1ec7u \u0111i\u1ec7n c\u1ef1c \u00e2m g\u1ed1c silicon s\u1ebd tr\u1edf th\u00e0nh tr\u1ecdng t\u00e2m c\u1ee7a ng\u00e0nh c\u00f4ng nghi\u1ec7p pin v\u00e0 \u0111\u1ea1t \u0111\u01b0\u1ee3c \u1ee9ng d\u1ee5ng th\u01b0\u01a1ng m\u1ea1i quy m\u00f4 l\u1edbn.<\/p>\n\n\n\n

Silic \u0111\u01b0\u1ee3c s\u1eed d\u1ee5ng trong v\u1eadt li\u1ec7u c\u1ef1c \u00e2m c\u1ee7a pin ch\u1ee7 y\u1ebfu \u1edf d\u1ea1ng nano, ch\u00fang ta c\u00f3 th\u1ec3 thu \u0111\u01b0\u1ee3c b\u1ed9t nano silic th\u00f4ng qua m\u00e1y nghi\u1ec1n, v\u00ed d\u1ee5: m\u00e1y nghi\u1ec1n bi<\/strong>.<\/a> \u0110\u1ed3ng th\u1eddi, \u0111\u1ec3 c\u1ea3i thi\u1ec7n hi\u1ec7u su\u1ea5t \u0111i\u1ec7n h\u00f3a c\u1ee7a v\u1eadt li\u1ec7u \u0111i\u1ec7n c\u1ef1c \u00e2m silicon, c\u1ea7n ph\u1ea3i c\u1ea3i ti\u1ebfn silicon. L\u00e0 nh\u00e0 s\u1ea3n xu\u1ea5t thi\u1ebft b\u1ecb b\u1ed9t chuy\u00ean nghi\u1ec7p, C\u00f4ng ty TNHH M\u00e1y m\u00f3c b\u1ed9t Qingdao Epic<\/em><\/strong><\/em><\/strong>.<\/a> c\u00f3 th\u1ec3 s\u1ea3n xu\u1ea5t m\u00e1y nghi\u1ec1n bi v\u00e0 h\u1ec7 th\u1ed1ng c\u1ea3i ti\u1ebfn l\u1edbp ph\u1ee7 b\u1ec1 m\u1eb7t<\/strong> \u0111\u1ec3 x\u1eed l\u00fd silicon. N\u1ebfu b\u1ea1n c\u00f3 b\u1ea5t k\u1ef3 nhu c\u1ea7u v\u00e0 c\u00e2u h\u1ecfi li\u00ean quan n\u00e0o, vui l\u00f2ng li\u00ean h\u1ec7 S\u1eed thi Thanh \u0110\u1ea3o<\/a><\/strong>.<\/p>\n\n\n\n

D\u01b0\u1edbi \u0111\u00e2y l\u00e0 h\u00ecnh \u1ea3nh \u0111\u1ec3 b\u1ea1n tham kh\u1ea3o.<\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n
\"\"<\/figure>","protected":false},"excerpt":{"rendered":"

V\u1edbi s\u1ef1 ph\u00e1t tri\u1ec3n nhanh ch\u00f3ng c\u1ee7a c\u00f4ng ngh\u1ec7 pin, silicon d\u1ea7n tr\u1edf th\u00e0nh v\u1eadt li\u1ec7u \u0111i\u1ec7n c\u1ef1c \u00e2m ti\u1ec1m n\u0103ng. Ngay t\u1eeb nh\u1eefng n\u0103m 1970, ng\u01b0\u1eddi ta \u0111\u00e3 ph\u00e1t hi\u1ec7n ra ph\u1ea3n \u1ee9ng \u0111i\u1ec7n h\u00f3a gi\u1eefa lithium (Li) v\u00e0 silicon nguy\u00ean t\u1ed1 [\u2026]<\/p>","protected":false},"author":1,"featured_media":15865,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"default","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","ast-disable-related-posts":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"set","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center 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center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"footnotes":""},"categories":[42],"tags":[],"class_list":["post-15836","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-industry-news"],"yoast_head":"\nSilicon with Grinding Mill Processed Applied in Negative Electrode<\/title>\n<meta name=\"description\" content=\"Through processing by grinding mill, eg: ball mill, silicon can be well used in negative elsctrode of battery.\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/www.quartz-grinding.com\/vi\/silicon-after-grinding-by-mill-can-be-used-in-negative-electrode\/\" \/>\n<meta property=\"og:locale\" content=\"vi_VN\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta 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